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Product Nature: Typical Property Homopolymers

 
Sample 200 300 500 4040/R7 4040/R9

Viscosity ASTM D 3236

@121 mPa.s 30.5 53.5 53.5 10.0 5.5
@140 mPa.s 21.0 37.0 39.0 7.5 4.5
@190 mPa.s 10.0 16.5 17.0 4.5 3.5
 
Mettler Drop Point ASTM D 3954

° C 118.3 118.8 120.4 112 92.5
 
Hardness ASTM D 1321

24 Hours dmm 3.8 3.6 2.7 5.7 7.1
 
Density ASTH D1505 g/cm3 0.94 0.94 0.99 0.99 0.99
 
DSC ASTM D 3418

Melt peak °C 88.3 91.7 91.5 84.1 83.3
99.3 99.3 116.3    
  116.2 116.7      
Melt enthalpy kj/kg 210.6 211.8 212.1 216.6 221.4
Crys peak °C 83.0 85.0 86.1 77.6 82.6
101.2 101.9 103.8 81.5  
 
Crys enthalpy kj/kg 205.7 206.3 218.5 205.5 214.6
%Crystallinity % 72 73 73 74 76
 
Molecular Weight (GPC)

Mw 1880 1400 2620 1060 940
Mn 1100 1050 1570 960 920
Mw/Mn 1.71 1.33 1.70 1.10 1.02
 
C13 NMR
number of branches per 1000 carbons
Methyl 1.48 1.44 1.00 1.41 1.33
1,3 - Diethyl 6.34 6.79 7.75 5.64 2.93
Butyl 1.69 1.65 0.85 0.94 0.63
Amyl 1.82 1.03   1.17 0.45
Hexyl+   as chain end 39.03 40.23 31.20 49.80 58.54
branches       1.15  

 

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